Reversible pH-dependent cyclization of hydroxy-substituted gem-chloronitroso compounds to isoxazoline N-oxides and 5,6-dihydro-4H-1,2-oxazine N-oxides
Roman S. Malykhin, Alexey Yu. Sukhorukov
Russ. Chem. Bull. 2024, 73,1303. doi: 10.1007/s11172-024-4247-1

3-Halo-5,6-dihydro-4H-1,2-oxazine N-oxides as synthetic equivalents of unsaturated nitrile oxides in the [3 + 2]-cycloaddition with arynes: synthesis of substituted 3-vinyl-1,2-benzisoxazoles
Alexander A. Lukoyanov, Svetlana A. Aksenova, Andrey A. Tabolin, Alexey Yu. Sukhorukov
Org. Biomol. Chem. 2024, 22, 3615. doi: 10.1039/D4OB00391H

An Intramolecular Nitroso-Meerwein-Ponndorf-Verley-Oppenauer Reaction to Access Fused Pyrrolidine Scaffolds
Roman S. Malykhin, Svetlana A. Aksenova, Alexey Yu. Sukhorukov
Org. Lett. 2024, 26, 450. doi: 10.1021/acs.orglett.3c03552

Catalytic Reductive Recyclization of Functionalized Isoxazoline N-Oxides to Pyrrolizidine-3-ones
Ilya V. Okladnikov, Svetlana A. Aksenova, Sema L. Ioffe, Alexey Yu. Sukhorukov
J. Org. Chem. 2024, 89, 379. doi: 10.1021/acs.joc.3c02154

Divergent synthesis of nitrocyclopropanes and isoxazoline N-oxides from nitro compounds and vinyl sulfonium salts
Pavel Yu. Ushakov, Ivan S. Golovanov, Sema L. Ioffe, Andrey A. Tabolin
Org. Chem. Front. 2024, 11, 315. doi: 10.1039/D3QO01664A

Crown-hydroxylamines are pH-dependent chelating N,O-ligands with a potential for aerobic oxidation catalysis
Vladislav K. Lesnikov, Ivan S. Golovanov, Yulia V. Nelyubina, Svetlana A. Aksenova, Alexey Yu. Sukhorukov
Nature Commun., 2023, 14, 7673. doi: 10.1038/s41467-023-43530-6

The Reduction of Carbonyl Compounds with Dicyclopentylzinc: A New Example of Asymmetric Amplifying Autocatalysis
Elena Sh. Saigitbatalova, Liliya Z. Latypova, Almaz A. Zagidullin, Almira R. Kurbangalieva, Ilya D. Gridnev
Int. J. Mol. Sci. 2023, 24(23), 17048. doi: 10.3390/ijms242317048

Nickel-Catalyzed Asymmetric Hydrogenation of α-Substituted Vinylphosphonates and Diarylvinylphosphine Oxides
Hanlin Wei, Hao Chen, Dr. Jianzhong Chen, Ilya D. Gridnev, Wanbin Zhang
Angew. Chem. Int. Ed., 2023, 62, e202214990. doi: 10.1002/anie.202214990

Co-Catalyzed Asymmetric Hydrogenation. The Same Enantioselection Pattern for Different Mechanisms
Ilya D. Gridnev
Int. J. Mol. Sci. 2023, 24(6), 5568. doi: 10.3390/ijms24065568

Development of Novel Indole and Coumarin Derivatives as Antibacterial Agents That Target Histidine Kinase in S. aureus
Lisha K. Poonacha, Rashmi Ramesh, Akshay Ravish, Arunkumar Mohan, Pradeep M. Uppar, Prashant K. Metri, Nanjunda Swamy Shivananju, Santosh L. Gaonkar, Shubha Gopal, Alexey Yu Sukhorukov, Vijay Pandey, Priya Babu Shubha, Basappa Basappa
Appl. Microbiol. 2023, 3(4), 1214. doi: 10.3390/applmicrobiol3040084

Reaction of Triazolic Aldehydes with Diisopropyl Zinc: Chirality Dissipation versus Amplification
Oleg A. Mikhaylov, Elena Sh. Saigitbatalova, Liliya Z. Latypova, Almira R. Kurbangalieva, Ilya D. Gridnev
Symmetry 2023, 15(7), 1382. doi: 10.3390/sym15071382

Reductive Denitrogenation of Six-membered Cyclic Nitronates to Densely Substituted Dihydrofurans with Raney® Nickel/AcOH System
Evgeny V. Pospelov, Alexander V. Zhirov, Baglan Kamidolla, Alexey Yu. Sukhorukov
Adv. Synth. Catal., 2023, 365, 2850. doi: 10.1002/adsc.202300573

Chapter Four - Fluoroheterocycle formation using fluoroalkynes and their synthetic equivalents
Andrey A. Tabolin
Advances in Heterocyclic Chemistry, 2023, 140, 125. doi: 10.1016/bs.aihch.2022.11.002

[3+3]-Annulation of Cyclic Nitronates with Vinyl Diazoacetates: Diastereoselective Synthesis of Partially Saturated [1,2]Oxazino[2,3-b][1,2]oxazines and Their Base-Promoted Ring Contraction to Pyrrolo[1,2-b][1,2]oxazine Derivatives
Yulia A. Antonova, Yulia V. Nelyubina, Sema L. Ioffe, Andrey A. Tabolin
Molecules, 2023, 28(7), 3025. doi: 10.3390/molecules28073025

Building Up a Piperazine Ring from a Primary Amino Group via Catalytic Reductive Cyclization of Dioximes
Evgeny V. Pospelov, Alexey Yu. Sukhorukov
Int. J. Mol. Sci., 2023, 24(14), 11794. doi: 10.3390/ijms241411794

Enhanced photostability of multication lead halide perovskites through the use of azaadamantane-based modifiers
V.V. Ozerova, N.A. Emelianov, L.G. Gutsev, D.V. Korchagin, G.V. Shilov, N.N. Dremova,
B.R. Ramachandran, A.Y. Sukhorukov, S.M. Aldoshin, L.A. Frolova, P.A. Troshin
Materials Today Chemistry. 2023, 30, 101590. doi: 10.1016/j.mtchem.2023.101590

Michael addition of P-nucleophiles to azoalkenes provides simple access to phosphine oxides bearing an alkylhydrazone moiety

Alexandr O. Kokuev, Alexey Yu. Sukhorukov
Front. Chem. 2023, 11, 1177680. doi: 10.3389/fchem.2023.1177680

Nitronate-aryne cycloaddition as a concise route to stereochemically complex fused benzisoxazolines and amino alcohols
Aleksander A. Lykoyanov, Andrey A. Tabolin, Yulia V. Nelyubina, Svetlana A. Aksenova, Alexey Yu. Sukhorukov
Org. Biomol. Chem., 2023, 21, 3871. doi: 10.1039/D3OB00235G

Global Search for Stable C₄H₅NO Compounds—Guinness Molecules and Stability Islands
Oleg A. Mikhaylov, Ilya D. Gridnev
Molecules, 2023, 28(2), 728. doi: 10.3390/molecules28020728

Interrupted Nef and Meyer Reactions: A Growing Point for Diversity-Oriented Synthesis Based on Nitro Compounds
Alexey Yu. Sukhorukov
Molecules, 2023, 28(2), 686. doi: 10.3390/molecules28020686

Interrupted Nef Reaction of Cyclic Nitronates: Diastereoselective Access to Densely Substituted α-Chloronitroso Compounds
Roman S. Malykhin, Yaroslav D. Boyko, Yulia V. Nelyubina, Sema L. Ioffe, Alexey Yu. Sukhorukov
J. Org. Chem., 2022, 87, 16617–16631. doi: 10.1021/acs.joc.2c02281

Small D-π-A-π-D organic dyes for near-infrared emitting OLEDs with excellent external quantum efficiency
Vladislav M.Korshunov, Timofey N. Chmovzh, Alexandra Ya Freidzon, Mikhail E. Minyaev, Artem D. Barkanov, Ivan S. Golovanov, Lyudmila V. Mikhalchenko, Igor C. Avetisov, Ilya V. Taydakov, Oleg A. Rakitin
Dyes and Pigments, 2022, 208, 110860. doi: 10.1016/j.dyepig.2022.110860

1,4,6,10-Tetraazaadamantanes (TAADs) with N-amino groups: synthesis and formation of boron chelates and host–guest complexes
Artem N. Semakin, Ivan S. Golovanov , Yulia V. Nelyubina, Alexey Yu. Sukhorukov
Beilstein J. Org. Chem., 2022, 18, 1424–1434. doi: 10.3762/bjoc.18.148

Iron(IV) complexes with tetraazaadamantane-based ligands: synthesis, structure, applications in dioxygen activation and labeling of biomolecules
Ivan S. Golovanov, Anton V. Leonov, Vladislav K. Lesnikov, Evgeny V. Pospelov, Kirill V. Frolov, Alexander A. Korlyukov, Yulia V. Nelyubina, Valentin V. Novikov, Alexey Yu. Sukhorukov 
Dalton Trans., 2022, 51, 4284-4296. doi: 10.1039/D1DT04104E

Tandem Michael addition/elimination – novel reactivity of pyridinium ylides in reaction with electron-deficient alkenes
Alexei N. Izmest'ev, Vladimir A. Motornov, Dmitry B. Vinogradov, Sema L. Ioffe,  Angelina N. Kravchenko, Galina A. Gazieva 
Org. Chem. Front., 2022, 9, 4998 - 5004. doi: 10.1039/D2QO00911K

Nickel-catalysed asymmetric hydrogenation of oximes
Bowen Li, Jianzhong Chen, Dan Liu, Ilya D. Gridnev, Wanbin Zhang
Nature Chemistry, 2022, 14, 920 - 927. doi: 10.1038/s41557-022-00971-8

London Disperse Interactions Assist Chiral Induction in the Soai Autoamplifying Reaction Provoked by 1- and 2-Aza[6]helicenes
Roman V. Zonov, Ilya D. Gridnev
Catalysts, 2022, 12(8), 859. doi: 10.3390/catal12080859

γ-Pyronecarbaldehyde-Based Practical Asymmetric Catalytic Synthesis of Chiral 2,4-Dihydroxycarboxylic Acids and α-Hydroxy-γ-lactones
Maxim V. Smirnov, Alexander S. Kucherenko, Ilya D. Gridnev, Alexander A. Korlyukov, Sergei G. Zlotin
Adv. Synth. Catal., 2022, 364, 3245. doi: 10.1002/adsc.202200859

Synthesis of 3-Haloisoxazolines by Deoxygenation of 3-Haloisoxazoline N-Oxides under Treatment with Acetyl Bromide
Anastasia A. Fadeeva, Sema L. Ioffe, Andrey A. Tabolin
ChemistrySelect, 2022, 7, e202202267. doi: 10.1002/slct.202202267

Ring Closure of Nitroalkylmalonates for the Synthesis of Isoxazolines under the Acylation Conditions
Yulia A. Antonova, Yulia V. Nelyubina, Sema L. Ioffe, Alexey Yu. Sukhorukov, Andrey A. Tabolin
Adv. Synth. Catal., 2022, 364, 2606. doi: 10.1002/adsc.202200420

Deoxygenative Arylation of 5,6-Dihydro-4H-1,2-oxazine-N-oxides with Arynes
Alexander A. Lukoyanov, Andrey A. Tabolin, Yulia V. Nelyubina, Sema L. Ioffe, Alexey Yu. Sukhorukov
J. Org. Chem., 2022, 87, 6838 – 6851. doi: 10.1021/acs.joc.2c00515

Tandem [3+2]-cycloaddition/homo-Baldwin rearrangement of silyl nitronates and donor-acceptor cyclopropenes. A novel approach to polysubstituted aziridines starting from nitro compounds
Yana I.Lichtenstein, Ivan S.Golovanov, Sema L.Ioffe, Andrey A.Tabolin
Tetrahedron, 2022, 110, 132693. doi: 10.1016/j.tet.2022.132693

Oxidative [3+2]-annulation of nitroalkenes and azolium ylides in the presence of Cu(II): efficient synthesis of [5,5]-annulated N-fused heterocycles
Vladimir A. Motornov, Andrey A. Tabolin, Sema L. Ioffe
New J. Chem., 2022, 46, 4134-4141. doi: 10.1039/D1NJ05332A

Piperazine-1,4-diol (PipzDiol): synthesis, stereodynamics and assembly of supramolecular hydrogen-bonded 2D networks
Vladislav K. Lesnikov, Yulia V. Nelyubina, Alexey Yu. Sukhorukov
New J. Chem., 2022, 46, 20386-20394. doi: 10.1039/D2NJ03012H

Asymmetric Synthesis of a Pyrrolizidinone-Based hNK₁ Antagonist through Reductive Ring Contraction of a Six-Membered Cyclic Nitronate
Ilya V. Okladnikov, Yaroslav D. Boyko, Yulia V. Nelyubina, Sema L. Ioffe, Alexey Yu. Sukhorukov
Eur. J. Org. Chem., 2022, e20220079. doi: 10.1002/ejoc.202200796

Regio- and diastereoselective access to densely functionalized ketones via the Boekelheide rearrangement of isoxazoline N-oxides
Pavel Yu. Ushakov,  Sema L. Ioffe,  Alexey Yu. Sukhorukov
Org. Biomol. Chem., 2022, 20, 5624 - 5637. doi: 10.1039/D2OB00787H

Synthesis of Bis(β-Oximinoalkyl)malonates and Their Catalytic Reductive Cyclization to Piperidines
Evgeny V. Pospelov,  Yaroslav D. Boyko,  Sema L. Ioffe,  Alexey Yu. Sukhorukov
Adv. Synth. Catal., 2022, 364, 2557. doi: 10.1002/adsc.202200424

Transition metal atoms grafted on the nanodiamonds surface: Identification and guest – host spin – spin interactions
Ilya D. Gridnev
Mend. Commun., 2022, 32, 2, 143 - 151. doi: 10.1016/j.mencom.2022.03.001

Birds of a Feather — Asymmetric Organocatalysis Meets Asymmetric Transition Metal Catalysis
Ilya D. Gridnev
Catalyst, 2022, 12(2), 214. doi: 10.3390/catal12020214

Recent advances in the application of ylide-like species in [4 + 1]-annulation reactions: an updated review
Pavel Yu. Ushakov, Sema L. Ioffe, Alexey Yu.Sukhorukov
Org. Chem. Front., 2022, 9, 5358 - 5382. doi: 10.1039/D2QO00698G

Addition of malonic esters to azoalkenes generated in situ from α-bromo- and α-chlorohydrazones
Aleksandr O.Kokuev, Sema L.Ioffe, Alexey Yu.Sukhorukov
Tetrahedron Lett., 2021, 83, 153414. doi: 10.1016/j.tetlet.2021.153414

Copper-Mediated Oxidative [3+2]-Annulation of Nitroalkenes and Ylides of 1,2-Diazines: Assembly of Functionalized Pyrrolo[1,2-b]pyridazines
Vladimir A. Motornov, Andrey A. Tabolin, Valentine G. Nenajdenko, Sema L. Ioffe
ChemistrySelect, 2021, 6, 9969. doi: 10.1002/slct.202103189

Construction of Saturated Oxazolo[3,2-b][1,2]oxazines via Tandem [3+2]-cycloaddition/[1,3]-Rearragement of Cyclic Nitronates and Ketenes
Roman S. Malykhin, Ivan S. Golovanov, Yulia V. Nelybina, Sema L. Ioffe and Alexey Yu. Sukhorukov
J. Org. Chem., 2021, 86, 16337–16348. doi: 10.1021/acs.joc.1c01744

Sequential Acylation/Silylation/Hetero-Claisen Rearrangement of Nitroalkanes for the Synthesis of Protected Hydroxyoxime Derivatives
Yulia A. Antonova, Prof. Dr. Sema L. Ioffe, Prof. Dr. Alexey Yu. Sukhorukov, Dr. Andrey A. Tabolin
Eur. J. Org. Chem., 2021, 2021, 3197. doi: 10.1002/ejoc.202100469

Dehydration of isoxazoline N-oxides under electrophilic conditions – An alternative approach toward 3-haloisoxazoles
Anastasia A. Fadeeva, Prof. Dr. Sema L. Ioffe, Dr. Andrey A. Tabolin
Tetrahedron Lett., 2021, 73, 153106. doi: 10.1016/j.tetlet.2021.153106

Sequential Formal [4+1]−Cycloaddition, C−H Functionalization and Suzuki–Miyaura Cross‐Coupling for the Synthesis of Trisubstituted Isoxazolines
Pavel Yu. Ushakov, Prof. Dr. Alexey Yu. Sukhorukov, Prof. Dr. Sema L. Ioffe, Dr. Andrey A. Tabolin
Eur. J. Org. Chem., 2021, 2021, 2680. doi: 10.1002/ejoc.202100313

Spectacular Enhancement of the Thermal and Photochemical Stability of MAPbI3 Perovskite Films Using Functionalized Tetraazaadamantane as a Molecular Modifier
Victoria V. Ozerova, Ivan S. Zhidkov, Aleksandra Boldyreva, Nadezhda N. Dremova, Nikita A. Emelianov, Gennady V. Shilov, Lyubov A. Frolova, Ernst Z. Kurmaev, Alexey Y. Sukhorukov, Sergey M. Aldoshin,  Pavel A. Troshin
Energies, 2021, 14, 3, 669. doi: 10.3390/en14030669

Revealing the Structure of Transition Metal Complexes of Formaldoxime
Ivan S. Golovanov, Roman S. Malykhin, Vladislav K. Lesnikov, Yulia V. Nelyubina, Valentin V. Novikov, Kirill V. Frolov, Andrey I. Stadnichenko, Evgeny V. Tretyakov, Sema L. Ioffe, and Alexey Yu. Sukhorukov
Inorg. Chem., 2021, 60, 8, 5523–5537. doi: 10.1021/acs.inorgchem.0c03362

Merging Boron with Nitrogen–Oxygen Bonds: A Review on BON Heterocycles
Ivan S. Golovanov, Alexey Yu. Sukhorukov
Top. Curr. Chem., 2021, 8, 379. doi: 10.1007/s41061-020-00317-3

Copper-catalyzed [3 + 2]-cycloaddition of α-halonitroalkenes with azomethine ylides: facile synthesis of multisubstituted pyrrolidines and pyrroles
Vladimir A. Motornov, Andrey A. Tabolin, Yulia V. Nelyubina, Valentine G. Nenajdenko, Sema L. Ioffe 
Org. Biomol. Chem., 2021,19, 3413-3427. doi: 10.1039/D1OB00146A

Recent Advances in the Stereoselective Synthesis of Pyrrolizidin‐3‐ones
Alexey Yu. Sukhorukov
Synthetic Approaches to Nonaromatic Nitrogen Heterocycles, Ch. 8. 2020, Wiley: Hoboken, pp. 179-223. doi: 10.1002/9781119708841.ch8

2,4,9‐Triazaadamantanes with “Clickable” Groups: Synthesis, Structure and Applications as Tripodal Platforms
Artem n. Semakin, Yulia V. Nelyubina, Sema L. Ioffe and Alexey Yu. Sukhorukov
Eur. J. Org. Chem., 2020, 43, 17, 6723-6735. doi: 10.1002/ejoc.202000832

Asymmetric Synthesis of Merck’s Potent hNK1 Antagonist and Its Stereoisomers via Tandem Acylation/[3,3]-Rearrangement of 1,2-Oxazine N-Oxides
Valentine S. Dorokhov, Yulia V. Nelyubina, Sema L. Ioffe and Alexey Yu. Sukhorukov
J. Org. Chem., 2020, 85, 17, 11060-11071. doi: 10.1021/acs.joc.0c01322

Acid‐Mediated Three Component Assembly of 4‐Fluoropyrazoles from α‐Fluoronitroalkenes, Hydrazines, and Aldehydes
Vladimir A. Motornov, Andrey A. Tabolin, Yulia V. Nelyubina, Valentine G. Nenajdenko and Sema L. Ioffe
Eur. J. Org. Chem., 2020, 2020, 32, 5211-5219. doi: 10.1002/ejoc.202000841

Chlorination of Conjugated Nitroalkenes with PhICl2 and SO2Cl2 for the Synthesis of α-Chloronitroalkenes
Anastasia A. Fadeeva, Sema L. Ioffe and Andrey A. Tabolin
Synthesis, 2020, 52(18), 2769-2688. doi: 10.1055/s-0040-1707396

The Cyclic Nitronate Route to Pharmaceutical Molecules: Synthesis of GSK’s Potent PDE4 Inhibitor as a Case Study
Evgeny V. Pospelov, Ivan S. Golovanov, Sema L. Ioffe and Alexey Yu. Sukhorukov
Molecules, 2020, 25(16), 3613. doi: 10.3390/molecules25163613

Nitro Compounds as Versatile Building Blocks for the Synthesis of Pharmaceutically Relevant Substances

Alexey Yu. Sukhorukov
Frontiers in Chemistry, 2020, Volume 8, 918 . doi: 10.3389/fchem.2020.595246

Catalytic Reductive Amination of Aldehydes and Ketones With Nitro Compounds: New Light on an Old Reaction
Alexey Yu. Sukhorukov
Frontiers in Chemistry, 2020, Volume 8, 215 . doi: 10.3389/fchem.2020.00215

Copper-mediated oxidative [3 + 2]-annulation of nitroalkenes and pyridinium imines: efficient synthesis of 3-fluoro- and 3-nitro-pyrazolo[1,5-a]pyridines
Vladimir A. Motornov, Andrey A. Tabolin, Yulia V. Nelyubina, Valentine G. Nenajdenko and Sema L. Ioffe
Org. Biomol. Chem. 2020,18, 1436-1448. doi: 10.1039/C9OB02668A

Umpolung of Enamines: An Overview on Strategies and Synthons
Alexey Yu. Sukhorukov
Synlett, 2020; 31(05), 439-449. doi: 10.1055/s-0037-1610741

C−H Reactivity of the α‐Position in Nitrones and Nitronates
Alexey Yu. Sukhorukov
Adv. Synth. Catal. 2020, 362, 724. doi: 10.1002/adsc.201900718

Synthesis of Isoxazolines from Nitroalkanes via a [4+1]‐Annulation Strategy
Pavel Yu. Ushakov, Elizaveta A. Khatuntseva, Yulia V. Nelyubina, Andrey A. Tabolin, Sema L. Ioffe, Alexey Yu. Sukhorukov
Adv. Synth. Catal. 2019, 361, 5322. doi: 10.1002/adsc.201901000

Nucleophilic Halogenation of Cyclic Nitronates: A General Access to 3-Halo-1,2-Oxazines
Roman S. Malykhin, Aleksandr O. Kokuev, Valentin S. Dorokhov, Yulia V. Nelyubina, Vladimir A. Tartakovsky, Andrey A. Tabolin, Sema L. Ioffe, Alexey Yu. Sukhorukov
J. Org. Chem. 2019, 84, 21, 13794-13806. doi: 10.1021/acs.joc.9b02010

Tandem double acylation/[3,3]-rearrangement of aliphatic nitro compounds: a route to α-oxygenated oxime derivatives
Antonova, Y. A.; Nelyubina, Y. V.; Sukhorukov, A. Y.; Ioffe, S. L.; Tabolin, A. A.
Org. Biomol. Chem. 2019, 17, 5997-6006. doi: 10.1039/C9OB01005J

Michael Addition of P-Nucleophiles to Conjugated Nitrosoalkenes
Naumovich, Y. A.; Ioffe, S. L.; Sukhorukov, A. Y.
J. Org. Chem. 2019, 84, 11, 7244–7254. doi: 10.1021/acs.joc.9b00924

Tandem Deoxygenation/Halogenation of N‐Oxides Under Acylation Conditions: Scope and In Situ IR Spectroscopic Study
Malykhin, R. S.; Golovanov, I. S.; Ioffe, S. L.; Sukhorukov, A. Y.
Eur. J. Org. Chem. 2019, 4139–4148. doi: 10.1002/ejoc.201900131

In Situ Generated Magnesium Cyanide as an Efficient Reagent for Nucleophilic Cyanation of Nitrosoalkenes and Parent Nitronates
Ushakov, P. Y.; Tabolin, A. A.; Ioffe, S. L.; Sukhorukov, A. Y.
Eur. J. Org. Chem. 2019, 1888–1892. doi: 10.1002/ejoc.201801761

Copper-mediated oxidative [3 + 2]-annulation of nitroalkenes and pyridinium ylides: general access to functionalized indolizines and efficient synthesis of 1-fluoroindolizines
Motornov, V. A.; Tabolin, A. A.; Nelyubina, Y. V; Nenajdenko, V. G.; Ioffe, S. L.
Org. Biomol. Chem. 2019, 17 (6), 1442–1454. doi: 10.1039/C8OB03126F

A New Algorithm for the Reactivity Umpolung of Aliphatic Nitro Compounds
Ioffe, S. L.; Khoroshutina, Y. A.; Smirnov, V. O.; Mikhaylov, A. A.
Kinet. Catal. 2018, 59 (6), 691–700. doi: 10.1134/S002315841806006X

α-Electrophilic Reactivity of Nitronates
Tabolin, A. A.; Sukhorukov, A. Y.; Ioffe, S. L.
Chem. Rec. 2018, 18 (10), 1489–1500. doi: 10.1002/tcr.201800009

Acylation of Nitronates: [3,3]-Sigmatropic Rearrangement of in Situ Generated N-Acyloxy, N-oxyenamines
Kokuev, A. O.; Antonova, Y. A.; Dorokhov, V. S.; Golovanov, I. S.; Nelyubina, Y. V.;
Tabolin, A. A.; Sukhorukov, A. Y.; Ioffe, S. L.
J. Org. Chem. 2018, 83 (18), 11057–11066. doi: 10.1021/acs.joc.8b01652

Fluoronitroalkenes in tandem [4 + 1]/[3 + 2]-cycloaddition: One-pot three-component assembly of fluorinated bicyclic nitroso acetals
Motornov, V. A.; Tabolin, A. A.; Novikov, R. A.; Nelyubina, Y. V.;
Nenajdenko, V. G.; Ioffe, S. L.
Org. Chem. Front. 2018, 5 (17), 2593–2599. doi: 10.1039/c8qo00623g

Exploiting Coupling of Boronic Acids with Triols for a pH-Dependent "Click-Declick" Chemistry
Golovanov, I. S.; Mazeina, G. S.; Nelyubina, Y. V.; Novikov, R. A.; Mazur, A. S.; Britvin, S. N.; Tartakovsky, V. A.; Ioffe, S. L.; Sukhorukov, A. Y.
J. Org. Chem. 2018, 83 (17), 9756–9773. doi: 10.1021/acs.joc.8b01296

Synthesis of unsaturated silyl nitronates via the silylation of conjugated nitroalkenes
Khotyantseva, E. A.; Tabolin, A. A.; Novikov, R. A.; Nelyubina, Y. V.; Ioffe, S. L.
Tetrahedron Lett. 2018, 59 (32), 3128–3131. doi: 10.1016/j.tetlet.2018.07.011

Green, Catalyst-Free Reaction of Indoles with β-Fluoro-β-nitrostyrenes in Water
Aldoshin, A. S.; Tabolin, A. A.; Ioffe, S. L.; Nenajdenko, V. G.
European J. Org. Chem. 2018, 3816–3825. doi: 10.1002/ejoc.201800385

Synthesis of 2,5-diaryl-4-halo-1,2,3-triazoles and comparative study of their fluorescent properties
Motornov, V. A.; Tabolin, A. A.; Novikov, R. A.; Shepel, N. E.; Nenajdenko, V. G.; Ioffe, S. L.
Tetrahedron 2018, 74 (28), 3897–3903. doi: 10.1016/j.tet.2018.05.071

Synthesis of α-Thiooximes by Addition of Thiols to N, N-Bis(oxy)-enamines: A Comparative Study of S-, N-, and O-Nucleophiles in Michael Reaction with Nitrosoalkene Species
Naumovich, Y. A.; Kokuev, A. O.; Sukhorukov, A. Y.; Ioffe, S. L.
Synlett 2018, 29 (10), 1334–1339. doi: 10.1055/s-0036-1591973

Diastereoselective synthesis and profiling of bicyclic imidazolidinone derivatives bearing a difluoromethylated catechol unit as potent phosphodiesterase 4 inhibitors
Dorokhov, V. S.; Golovanov, I. S.; Tartakovsky, V. A.; Sukhorukov, A. Y.; Ioffe, S. L.
Org. Biomol. Chem. 2018, 16, 6900–6908. doi: 10.1039/C8OB01039K

A Novel Entry to 3,4,5-Trisubstituted 2-Pyrrolidones from Isoxazoline-N-oxides
Zhmurov, P. A.; Ushakov, P. Y.; Novikov, R. A.; Sukhorukov, A. Y.; Ioffe, S. L.
Synlett 2018, 29 (14), 1871–1874. doi: 10.1055/s-0037-1610213

Synthesis and Regioselective N-2 Functionalization of 4-Fluoro-5-aryl-1,2,3-NH-triazoles
Motornov, V. A.; Tabolin, A. A.; Novikov, R. A.; Nelyubina, Y. V.; Ioffe, S. L.; Smolyar, I. V.; Nenajdenko, V. G.
European J. Org. Chem. 2017, 2017 (46), 6851–6860. doi: 10.1002/ejoc.201701338

Addition of HO-Acids to N,N-Bis(oxy)enamines: Mechanism, Scope and Application to the Synthesis of Pharmaceuticals
Naumovich, Y. A.; Golovanov, I. S.; Sukhorukov, A. Y.; Ioffe, S. L.
European J. Org. Chem. 2017, 2017 (41), 6209–6227. doi: 10.1002/ejoc.201701266

Conjugated nitrosoalkenes as Michael acceptors in carbon-carbon bond forming reactions: A review and perspective
Boyko, Y. D.; Dorokhov, V. S.; Sukhorukov, A. Y.; Ioffe, S. L.
Beilstein J. Org. Chem. 2017, 13, 2214–2234. doi: 10.3762/bjoc.13.220

Synthesis and Structure of N,N-Dinitroamidoborane Complexes
Shitov, O. P.; Tartakovsky, V. A.; Golovanov, I. S.; Sukhorukov, A. Y.; Ioffe, S. L.
Chem. - An Asian J. 2017, 12 (17), 2237–2244. doi: 10.1002/asia.201700603

Organic and hybrid systems: from science to practice
Ananikov, V. P.; Eremin, D. B.; Yakukhnov, S. A.; Dilman, A. D.; Levin, V. V.; Egorov, M. P.; Karlov, S. S.; Kustov, L. M.; Tarasov, A. L.; Greish, A. A.; Shesterkina, A. A.; Sakharov, A. M.; Nysenko, Z. N.; Sheremetev, A. B.; Stakheev, A. Y.; Mashkovsky, I. S.;
Sukhorukov, A. Y.; Ioffe, S. L.; Terent'ev, A. O.; Vil, V. A.; Tomilov, Y. V.; Novikov, R. A.;
Zlotin, S. G.; Kucherenko, A. S.; Ustyuzhanina, N. E.; Krylov, V. B.; Tsvetkov, Y. E.;
Gening, M. L.; Nifantiev, N. E.
Mendeleev Commun. 2017, 27 (5), 425–438. doi: 10.1016/j.mencom.2017.09.001

Recent Advances in the Synthesis and Chemistry of Nitronates
Tabolin, A. A.; Sukhorukov, A. Y.; Ioffe, S. L.; Dilman, A. D.
Synth. 2017, 49 (15), 3255–3268. doi: 10.1055/s-0036-1589063

Radical Nitration-Debromination of α-Bromo-α-fluoroalkenes as a Stereoselective Route to Aromatic α-Fluoronitroalkenes - Functionalized Fluorinated Building Blocks for Organic Synthesis
Motornov, V. A.; Muzalevskiy, V. M.; Tabolin, A. A.; Novikov, R. A.; Nelyubina, Y. V.; Nenajdenko, V. G.; Ioffe, S. L.
J. Org. Chem. 2017, 82 (10), 5274–5284. doi: 10.1021/acs.joc.7b00578

Divergent Reactivity of In Situ Generated Metal Azides: Reaction with N,N-Bis(oxy)enamines as a Case Study
Zhmurov, P. A.; Khoroshutina, Y. A.; Novikov, R. A.; Golovanov, I. S.; Sukhorukov, A. Y.; Ioffe, S. L.
Chem. - A Eur. J. 2017, 23 (19), 4570–4578. doi: 10.1002/chem.201605390

Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
Semakin, A. N.; Kokuev, A. O.; Nelyubina, Y. V.; Sukhorukov, A. Y.; Zhmurov, P. A.;
Ioffe, S. L.; Tartakovsky, V. A.
Beilstein J. Org. Chem. 2016, 12, 2471–2477. doi: 10.3762/bjoc.12.241

Synthesis of 1,4,6,10-tetraazaadamantane quaternary derivatives
Semakin, A. N.; Golovanov, I. S.; Sukhorukov, A. Y.; Ioffe, S. L.; Tartakovsky, V. A.
Russ. Chem. Bull. 2016, 65 (9), 2270–2277. doi: 10.1007/s11172-016-1577-7

Synthesis and chemical transformations of six/six-membered bicyclic nitroso acetals
Tabolin, A. A.; Gorbacheva, E. O.; Novikov, R. A.; Khoroshutina, Y. A.;
Nelyubina, Y. V.; Ioffe, S. L.
Russ. Chem. Bull. 2016, 65 (9), 2243–2259. doi: 10.1007/s11172-016-1575-9

Small Ring Compounds and N-oxides: Cycloadditions and Related Processes
Tabolin, A. A.; Ioffe, S. L.
Isr. J. Chem. 2016, 56 (6–7), 385–398. doi: 10.1002/ijch.201500082

Metal-assisted addition of a nitrate anion to bis(oxy)enamines. A general approach to the synthesis of α-nitroxy-oxime derivatives from nitronates
Naumovich, Y. A.; Buckland, V. E.; Sen'ko, D. A.; Nelyubina, Y. V.; Khoroshutina, Y. A.; Sukhorukov, A. Y.; Ioffe, S. L.
Org. Biomol. Chem. 2016, 14 (16), 3963–3974. doi: 10.1039/c6ob00388e

Tandem Pd-catalyzed C-C coupling/recyclization of 2-(2-bromoaryl)cyclopropane-1,1-dicarboxylates with primary nitro alkanes
Mikhaylov, A. A.; Dilman, A. D.; Novikov, R. A.; Khoroshutina, Y. A.; Struchkova, M. I.; Arkhipov, D. E.; Nelyubina, Y. V.; Tabolin, A. A.; Ioffe, S. L.
Tetrahedron Lett. 2016, 57 (1), 11–14. doi: 10.1016/j.tetlet.2015.10.091

Six-Membered Cyclic Nitroso Acetals: Synthesis and Studies of the Nitrogen Inversion Process of N-Silyloxy-3,6-dihydro-2H-1,2-oxazines
Shved, A. S.; Tabolin, A. A.; Novikov, R. A.; Nelyubina, Y. V.; Timofeev, V. P.; Ioffe, S. L.
European J. Org. Chem. 2016, 5569–5578. doi: 10.1002/ejoc.201600952

Oximinoalkylamines as ligands for Cu-assisted azide-acetylene cycloaddition
Semakin, A. N.; Agababyan, D. P.; Kim, S.; Lee, S.; Sukhorukov, A. Y.; Fedina, K. G.; Oh, J.; Ioffe, S. L.
Tetrahedron Lett. 2015, 56 (46), 6335–6339. doi: 10.1016/j.tetlet.2015.09.106

Stereoselective Synthesis of Spirocyclic Nitronates by SnCl₄-promoted Reaction of Nitroalkenes with C-2 Substituted 4-methylidene-1,3-dioxolane
Mikhaylov, A. A.; Zhmurov, P. A.; Naumova, A. S.; Khoroshutina, Y. A.; Sukhorukov, A. Y.; Ioffe, S. L.
Mendeleev Commun. 2015, 25 (6), 449–451. doi: 10.1016/j.mencom.2015.11.017

Synthesis of B,O,N-Doped Adamantanes and Diamantanes by Condensation of Oximes with Boronic Acids
Golovanov, I. S.; Sukhorukov, A. Y.; Nelyubina, Y. V.; Khomutova, Y. A.; Ioffe, S. L.; Tartakovsky, V. A.
J. Org. Chem. 2015, 80 (13), 6728–6736. doi: 10.1021/acs.joc.5b00892

Advances in the synthesis of 7-(3-cyclopentyloxy-4-methoxyphenyl)-hexahydro-3H-pyrrolizin-3-one (Pyrromilast)-a promising agent for treatment of chronic obstructive pulmonary disease
Boyko, Y. D.; Sukhorukov, A. Y.; Ioffe, S. L.; Tartakovsky, V. A.
Russ. Chem. Bull. 2015, 64 (6), 1240–1248. doi: 10.1007/s11172-015-1007-2

Formal [3+3]-cycloaddition of 3-methyl-5,6-dihydro-4H-1,2-oxazine-N-oxides with cyclopropane dicarboxylates under hyperbaric conditions
Tabolin, A. A.; Novikov, R. A.; Khomutova, Y. A.; Zharov, A. A.; Stashina, G. A.; Nelyubina, Y. V.; Tomilov, Y. V.; Ioffe, S. L.
Tetrahedron Lett. 2015, 56 (16), 2102–2105. doi: 10.1016/j.tetlet.2015.03.011

Synthesis of Tris(-oximinoalkyl)amines, New Tripodal N4 Ligands
Dorokhov, V. S.; Jung, H.; Kang, G.; Andreev, Y. A.; Semakin, A. N.; Oh, J.;
Sukhorukov, A. Y.; Ioffe, S. L.; Semenov, S. E.
Synth. Commun. 2015, 45 (11), 1362–1366. doi: 10.1080/00397911.2015.1021424